Chromanik SunShell Biphenyl UHPLC & HPLC column, 2.6μm, 150 mm Length x 3 mm ID
Product Number: C86371
Trifuctional silyl-reagent used - Sunniest Biphenyl and SunShell Biphenyl use biphenyltrichlorosilane reagents. Trifunctional reagents have the characteristic of improving acid stability.
- The two benzene rings of the biphenyl group are twisted about 45 degree, and the biphenyl group shows different separation from the phenyl group alone.
- Even when an aqueous mobile phase containing no organic solvent is used, there is no decrease in retention, and separation with high reproducibility of retention time is achieved.
- Greater retention of polar compounds such as caffeine.
Biphenyl UHPLC & HPLC columns are available in:
- Sunshell Columns - Core shell particle
- Sunniest Columns - Fully porous particle
Features of Biphenyl
- The two benzene rings of the biphenyl group are twisted about 45 degree, and the biphenyl group shows different separation from the phenyl group alone.
- Even when an aqueous mobile phase containing no organic solvent is used, there is no decrease in retention, and separation with high reproducibility of retention time is achieved.
- Greater retention of polar compounds such as caffeine.
The SunShell column has not only an inert surface but also high stability due to deactivated silanol groups. SunShell 2.6 μm column can be used on both HPLC and UHPLC because it shows 2 times lower back presure than sub 2 μm column.
SunShell C18 2.6 μm sized 100x4.6mm has the same performance as a totally porous C18 5 μm sized 250x4.6mm, so that the same separation can be achieved by both columns without changing the separation condition consequently analysis time reduces one third.
SunShell series are not only C18 column which is optional as the first choice column but also the other column of various separation properties. Hydrogen bond capacity, hydrophobicity, steric selectivity and feature are shown in the table.
Excellent end-capping
Hexamethyltri siloxane is used as an end-capping reagent. This reagent can stretch and be bent like a Geometrid caterpillar as shown in the figure, so that a functional group on the tip of the reagent can bond with a silanol group which is located anywhere.
This end-capping made influence of residual silanol groups the lowest. Then not only good peak shape of a basic compound but also excellent stability was achieved by this unique end-capping.
Range of SunShell Columns and Specifications:
hydrogen bond capacity Caffeine / Phenol |
Hydrophobicity Amylbenzene / Butylbenzene |
Stereoselectivity Triphenylene / o-Terphenyl |
Feuture | |
C18 | 0.39 | 1.6 | 1.46 | First Choice! |
PFP | 1 | 1.31 | 2.38 | Halide, caion and structural isomers! |
Phenyl | 1 | 1.48 | 1.01 | Aromatic compound! |
C8 | 0.32 | 1.46 | 1.08 | High-speed analysis of non-polar compounds! |
RP-AQUA | 0.52 | 1.52 | 1.3 | 100% aqueaus mobile phase is available! |
C18-WP | 0.4 | 1.55 | 1.35 | Peptides and protains! |
Characteristics of SunShell C18 - 2 μm, 2.6 μm, 5 μm
Core shell silica | C18 (USP L1) | |||||||
Particle size | Pore diameter | Specific surface area | Carbon content | Bonded phase | End-capping | Maximum operating pressure (a) | Available pH range | |
SunShell C18 | 2.0 μm | 9 nm | 120 m2 /g | 6.5% | C18 | Sunniest endcapping | 100 MPa or 14504 psi | 1.5 - 10 |
SunShell C18 | 2.6 μm | 9 nm | 150 m2 /g | 7% | C18 | Sunniest endcapping | 60 MPa or 8,570 psi | 1.5 - 10 |
SunShell C18 | 3.5 μm | 9 nm | 120 m2 /g | 6.5% | C18 | Sunniest endcapping | 60 MPa or 8,570 psi | 1.5 - 10 |
SunShell C18 | 4.6 μm | 9 nm | 90 m2 /g | 5.5% | C18 | Sunniest endcapping | 50 MPa or 7,141 psi50 MPa or 7,141 psi | 1.5 - 10 |
(a) Unless otherwise specified in the column test report
SunShell C18-WP, RP-AQUA, C8, Phenyl, PFP, PFP&C18, 2.6 SunShell C18-WP, RP-AQUA, C8, Phenyl, PFP, PFP&C18, 2.6 μm - Pentafluoropheny
Core shell silica | Bonding phase | ||||||||
Particle size | Pore diameter | Specific surface area | Carbon content | Bonded phase | USP L line | End-capping | Maximum operating pressur (a) | Available pH range | |
SunShell C18 | 2.6 μm | 9 nm | 150 m2 /g | 7% | C18 | L1 | Sunniest endcapping | 60 MPa | 1.5 - 10 |
SunShell C18-WP | 2.6 μm | 16 nm | 90 m2 /g | 5% | C18 | L1 | Sunniest endcapping | 60 MPa | 1.5 - 10 |
SunShell RP-AQUA | 2.6 μm | 16 nm | 90 m2 /g | 4% | C30 | L62 | Sunniest endcapping | 60 MPa | 2 – 8 b |
SunShell C8 | 2.6 μm | 9 nm | 150 m2 /g | 4.5% | C8 | L7 | Sunniest endcapping | 60 MPa | 1.5 - 9 |
SunShell Pheny | 2.6 μm | 9 nm | 150 m2 /g | 5% | Phenylhexyl | L11 | Sunniest endcapping | 60 MPa | 1.5 - 9 |
SunShell Biphenyl | 2.6 μm | 9 nm | 150 m2 /g | 5% | Biphenyl | L11 | Sunniest endcapping | 60 MPa | 1.5 - 9 |
SunShell PFP | 2.6 μm | 9 nm | 150 m2 /g | 4.5% | Pentafluorophenyl | L43 | TMS endcapping | 60 MPa | 2 - 8 |
SunShell PFP & C18 | 2.6 μm | 9 nm | 150 m2 /g | 6% | Pentafluorophenyl + C18 | L43 | TMS endcapping | 60 MPa | 2 - 8 |
(a) Unless otherwise specified in the column test report (b) Under 100% aqueous condition
Specifications of SunShell C30
Core shell silica | Bonding phase | ||||||||
Particle size (μm) | Core size (μm) | Pore size (nm) | Specific surface area (m2 /g) | Carbon loading (%) | Ligand | USP L category | End-capping | Maximum pressure (a) | pH range |
2.6 | 1.6 | 12 | 95 | 7 | C30 | L62 | TMS | 60 MPa | 1.5 - 9 |
a) Unless otherwise specified in the column test report
Specifications for SunShell 2.6 μm C18-WP, HFC18-16, HFC18-30, C8-30, C8-30HT, C4-30, C4-100
For separation of peptides and proteins
Core shell silica | Bonding phase | |||||||||
Particle size | Pore diameter | Specific surface area | Stationary phase | Carbon content | Ligand density | End-capping | Maximum operating pressure (a) | Available pH range | USP L line | |
SunShell C18-WP | 2.6 μm | 16 nm | 90 m2 /g | C18 | 5 % | 2.5 μmol/m2 | Sunniest endcapping | 60 MPa or 8,570 psi | 1.5 - 10 | L1 |
SunShell HFC18-16 | 2.6 μm | 16 nm | 90 m2 /g | C18 | 2.5% | 1.2 μmol/m2 | Sunniest endcapping | 60 MPa or 8,570 psi | 1.5 – 9 | L1 |
SunShell HFC18-30 | 2.6 μm | 30 nm | 40 m2 /g | C18 | 1.3% | 1.2 μmol/m2 | Sunniest endcapping | 60 MPaa or 8,570 psi b | 1.5 - 9 | L1 |
SunShell C8-30 | 2.6 μm | 30 nm | 40 m2 /g | C8 | 1.2% | 2.5 μmol/m2 | Sunniest endcapping | 60 MPaa or 8,570 psi b | 1.5 – 9 | L7 |
SunShell C8-30HT | 3.4 μm | 30 nm | 15 m2 /g | C8 | 0.5% | 2.5 μmol/m2 | Sunniest endcapping | 60 MPaa or 8,570 psi b | 1.5 – 9 | L7 |
SunShell C4-30 | 2.6 μm | 30 nm | 40 m2 /g | C4 | 0.9% | 3 μmol/m2 | Sunniest endcapping | 60 MPaa or 8,570 psi b | 1.5 – 8 | L26 |
SunShell C4-100 | 2.6 μm | 100 nm | 22 m2 /g | C4 | 0.6% | 3 μmol/m2 | Sunniest endcapping | 60 MPaa or 8,570 psi b | 1.5 – 8 | L26 |
a) Unless otherwise specified in the column test report (b) Under 100% aqueous condition
Note: The SunShell HFC18-30, C8-30, and C4-30 columns will be discontinued once the packaging materials are out of stock
Characteristics of SunShell 2-EP - For Supercritical fluid Chromatography
Core shell silica | ||||||||
Particle size | Pore diameter | Specific surface area | Carbon content | Bonded phase | Endcapping | Maximum operating pressure (a) | Available pH range | |
SunShell 2-EP | 2.6 μm | 9 nm | 150 m2 /g | 2.5% | 2-Ethylpyridine | no | 60 MPa or 8,570 psi | 2 – 7.5 |
a) Unless otherwise specified in the column test report
SunShell HILIC-Amide, HILIC-S, 2.6 μm - For Hydrophilic Interaction Chromatography
Core shell silica | Bonded phase | |||||||||
Particle size | Core size | Pore diameter | Specific surface area | Carbon content | Bonded phase | Endcapping | Maximum operating pressure (a) | Available pH range | USP category | |
SunShell HILIC-Amide | 2.6 μm | 1.6 μm | 9 nm | 150 m2 /g | 3% | Amide | No | 60 MPa or 8,570 psi | L68 | 2 - 8 |
SunShell HILIC-S | 2.6 μm | 1.6 μm | 9 nm | 150 m2 /g | 0% | Bare silica | No | 60 MPa or 8,570 psi | L3 | 1 - 5 |
(a) Unless otherwise specified in the column test report
- Model: C86371
- Manufactured by: ChromaNik Technologies Inc